|
Professor
J.H.P. Utley
School of Biological & Chemical
Sciences
Queen Mary, University of London Mile End Road, London E1 4NS, UK E-mail : J.Utley@qmul.ac.uk |
Professor
J.H.P. Utley, BSc PhD DSc
(Lond) CChem FRSC : is an
Emeritus Professor in Organic Chemistry and until October 1st 2001 held the
established Chair of Organic Chemistry in the Department of Chemistry at Queen
Mary, University of London.
Professor Jim Utley has acted as Head of Chemistry (1987-91,1997-99), as Dean of the Faculty of Natural Sciences
(1991-94) and as a member of College Council (1991-94). He has held positions
as Professeur Invité at the
Ecole Normale Supérieure, Paris, (1995) and as Guest Professor at the
Universities of Texas at Austin (1995), Westfälischen
Wilhelms-Universität, Münster
(1985) and of Aarhus (1973).
He was the recipient, in 2000, of the 4th Manuel M. Baizer Award of the Organic and Biological Division of the
Electrochemical Society (US). Citation, "In recognition
of outstanding research contributions in the field of organic electrochemistry".
Research areas: Organic electrochemistry applied to
synthetic methodology and the study of reaction mechanisms.
Professor
Utley's research is mainly concerned with reactive intermediates which may be
generated electrochemically. The advantages of this approach stem from the
non-thermal activation and the clean (minimum reagent) conditions. Because
activation is by electron transfer at ambient temperatures difficult processes
can be driven under chemically mild conditions. And because oxidation and
reduction is achieved without chemical reagents the processes can be
environmentally friendly ("clean synthesis"). These aspects are attracting
much current attention both nationally and worldwide. Advances in reactor
engineering also mean that promising reactions may usually be scaled up for
industrial use.
Professor
Utley no longer supervises researchers but he acts as a consultant and
collaborates with colleagues on matters of electroorganic
chemistry.
Particular aspects that have been pursued by the Queen Mary
Organic Electrochemistry Group include:
·
Recent Trends in
Organic Electrosynthesis, J.H.P. Utley, Chem. Soc. Reviews, 1997, 26,
157-168
·
Utley J H P;
Little, R. D.; Nielsen, M. F. Reductive Coupling. In Organic
Electrochemistry, 5th ed.; Hammerich, O., Speiser, B., Eds.; Taylor and Francis: 2013.
·
Utley J H P;
Wyatt, P. B.; Nielsen, M. F. Electrogenerated Bases
and Nucleophiles. In Organic
Electrochemistry, 5th ed.; Hammerich, O., Speiser, B., Eds.; Taylor and Francis: 2013.
·
Hammerich, O.; Utley J H P; Anodic Substitution and Addition.
In Organic Electrochemistry, 5th ed.;
Hammerich, O., Speiser, B.,
Eds.; Taylor and Francis: 2013.
·
Eru,
E.; Hawkes, G. E.; Utley, J. H. P.; Wyatt, P. B. Electroorganic Reactions .41. Diels-Alder Reactions of O-Quinodimethanes from the Cathodic
Reduction of Alpha,Alpha'-Dibromo-1,2-Dialkylbenzenes.
Tetrahedron 1995, 51 (10), 3033-3044.
·
Electrorganic Reactions. Part 54. Quinodimethane
Chemistry. Part 2. Electrogeneration and Reactivity
of ortho-Quinodimethanes, J.H.P. Utley, S. Ramesh, X. Salvatella, S. Szunerits, M. Motevalli and M. F.
Nielsen, J. Chem. Soc., Perkin Trans. 2, 2001, 153-163
Polymers:
·
Utley, J. H. P.; Gao, Y. P.; Gruber, J.; Lines, R. Electrochemical Route to Xylylene Polymers and Copolymers Via Cathodically
Generated Quinodimethanes - Preparative and
Structural Aspects. Journal of Materials Chemistry 1995, 5
(9), 1297-1308.
·
Utley, JH P;
Gruber, J. Electrochemical synthesis of poly(p-xylylenes) (PPXs) and poly(p-phenylene
vinylenes) (PPVs) and the study of xylylene (quinodimethane)
intermediates; an underrated approach. J. Materials Chem. 2002, 12, 1613-1624.
·
Janssen, R. G.;
Utley J H P; Carre, E.; Simon, E.; Schirmer, H. Electrorganic
Reactions. Part 55. Quinodimethane
Chemistry. Part 3. Transition metal complexes as inter and intra-molecular redox catalysts for the electrosynthesis of poly-p-xylylene (PPX) polymers and oligomers.
J. Chem. Soc., Perkin Trans. 2 2001, 1573-1584.
Reductive coupling:
·
Fussing,
I.; Gullu, M.; Hammerich,
O.; Hussain, A.; Nielsen, M. F.; Utley, J. H. P. Utley
J
Stereoselectivity and mechanism in the electrohydrodimerisation of esters of cinnamic
acid. Journal of
the Chemical Society-Perkin Transactions 2 1996, (4), 649-658.
·
Utley,
J. H. P.; Gullu, M.; De Matteis,
C. I.; Motevalli, M.; Nielsen, M. F. Electroorganic Reactions .45. the
Highly Stereoselective Electrochemical Hydrodimerisation
of Methyl 4-tert-Butylcyclohex-1-Enecarboxylate. Tetrahedron 1995,
51 (43), 11873-11882.
C-O cleavage:
·
Sopher, D. W.; Utley, J. H. P. Alkene
Formation in the Cathodic Reduction of Oxalates. Journal
of the Chemical Society-Chemical Communications 1981, (3), 134-136.
·
Ellis, K. J.;
Islam, N.; Smith, C. Z.; Sopher, D. W.; Utley, J. H.
P.; Chum, H. L. Approaches to the Electrochemical Cleavage of Carbon-Oxygen
Bonds. Journal of the Electrochemical Society 1984, 131
(3), C105.
·
Riley, J. H.; Sopher, D. W.; Utley, J. H. P.; Walton, D. J. Electroorganic Reactions .21. the
Formation of Alkenes and Alkanes from Pinacols - the Electrochemical Cleavage of Cyclic
Carbonates and Aryl Boronates. Journal of Chemical
Research-S 1982, (12), 326-327.
·
Utley, J. H. P.; Ramesh, S. Electroorganic
Reactions. Part 58. Revisiting the cleavage of oxalate ester radical-anions, Arkivoc 2003, 18-26.
Lignins:
·
Pardini,
V. L.; Smith, C. Z.; Utley, J. H. P.; Vargas, R. R.; Viertler,
H. Electroorganic Reactions .38. Mechanism of Electrooxidative Cleavage of Lignin Model Dimers. Journal of Organic Chemistry 1991, 56
(26), 7305-7313.
·
Smith,
C. Z.; Utley, J. H. P.; Hammond, J. K. Electro-organic reactions. Part 61. The
electro-oxidative conversion at laboratory scale of a lignosulfonate into
vanillin in an FM01 filter press flow reactor: preparative and mechanistic
aspects, Journal of Applied Electrochemistry 2011, 41 (4),
363-375.
Electrogenerated bases:
·
Alonso, A. M.; Horcajada, R.; Motevalli, M.; Utley,
J. H. P.; Wyatt, P. B. Electroorganic Reactions Part
60. The reactivity, as electrogenerated bases, of
chiral and achiral phenazine
radical-anions, including application in asymmetric deprotonation. Organic
& Biomolecular Chemistry 2005, 3
(15), 2842-2847.
·
Generation of strong homochiral
bases by electrochemical reduction of phenazine
derivatives, A. Mateo Alonso, H. Groombridge, R. Horcajada, R. Mandalia, M. Motevalli, J. H. P. Utley and P. B. Wyatt, Chem. Commun., 2004, 412 –413.
·
Bettencourt, A.
P.; Freitas, A. M.; Montenegro, M. I.; Nielsen, M.
F.; Utley, J. H. P. Kinetics of proton transfer from phosphonium
ions to electrogenerated bases: polar, steric and structural influences on kinetic acidity and basicity. Journal of the Chemical Society-Perkin
Transactions 2 1998, (3), 515-522.
Last
update: December 12th 2012